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Although the RAVE method usually works, I've my own way of bleeding the air out of the system. Have a go at this:

You can start filling through the top hose connector on the inlet manifold and once it won't take any more there (preferably fill with neat anti-freeze), connect the hose and start filling at the header tank. Rather than rely on the air finding it's way out of the bleed at the top of the radiator, I usually take the pipe off that and leave it open. Sooner or later, coolant will start to dribble out of the nipple on the radiator. When it does, squeeze the top hose, put a finger over the nipple and release the top hose. That will push air out of the nipple but suck coolant in from the header tank as the hose returns to normal shape. Just keep on doing that, squeeze, plug the hole, release, squeeze, plug the hole, release, etc. You'll notice the level going down in the header tank quite quickly and every time you squeeze the top hose you'll hear bubbling in the pipes too. Just keep topping up the header tank until you can squeeze the top hose and not hear any bubbling somewhere in the bowels of the engine.

Then connect the bleed pipe and give the top hose another squeeze. You should see a jet of coolant inside the top of the tank from the bleed. Give it a couple of more goes. Squeeze the top hose, finger over the hole just inside the header tank, release the hose. Keep doing that until you can't hear any bubbling. Then, and only then, start the engine. Let it idle with the header tank cap off and watch for any air bubbles appearing in there. Again, a quick squeeze on the top hose should shift anything still in there. The level will rise as the heat causes the coolant to expand but if it starts overflowing, you've still got air in there somewhere (air expands far more than coolant so any air locks will expand and force the coolant out). Once the stat opens (top hose gets hot), the level may drop, just keep topping it up. If you've got rid of the air, you should see a nice steady stream out of the bleed pipe into the header and the level will stay steady. If the level drops or rises rapidly you've still not got all the air out so switch the engine off and do a bit more squeeze and plug. When you are happy there's no more air in there, put the cap on the header tank.

The car wants to be sitting level or if this isn't possible get it so the front right corner is highest so any air will rise up to the header tank. They can be a bit of a bastard to bleed completely. I bought mine with a blown head gasket, changed that, filled the header tank up just like I would on any other car and took it for a run down the road. I managed about 3 miles before the gauge shot up to the top, the red light came on and there was steam coming out of the header tank overflow. Fortunately, I still had a gallon of water in the boot so let the pressure escape, refilled it and limped home before reading the book and spending a bit more time doing it properly.

Have fun

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Thanks . Cant believe what a bitch it is.

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Not counting my chickens but I managed a high speed run without glitch.

I wasn't getting any bubbling when trying to bleed but still wasnt getting a steady flow.

I decided to disconnected the hose from the header that goes to the metal pipe and rejoins with the hose as apparently rust can cause it to clog.

It seemed to flow freely when disconnected but maybe it dislodged something in doing so as I was able to rev the car for ages with the cap off without it overflowing , it would start to rise slowly at idle though when revved again would flow as it should without overflowing.
Left it a few hours put the cap back on and it seems ok as I wouldn't get passed a mile before and managed about 5 just now as I didnt want to push my luck with no sign of overheating or overflowing.

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Great! <br>
Once it's cooled, top it up again (and possibly again and again). Hopefully all will be well...

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Poke a bit of thin wire through the pipe going into the header tank, they can clog up especially if the engine has been run with plain water or very little antifreeze.

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No no nooooooooooooooo.

Only managed a couple of miles . Checked the coolant level this morning and it was fine. What the hell.
Just bled again whilst at the side of the road and its flowing nicely, if it fails again then I will have to change the thermostat just to rule that out .

I was so hoping its an air block but I have hot air and its flowing ok with the cap off. Its overheated so many times now that the head gasket will probably need changing anyway.

I will give that a go myself if all else fails as I will have nothing to loose trying.

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Are you saying you are able to take the cap off when it has overheated? If you can it isn't a head gasket problem as it would have so much pressure in the system it will end up everywhere.

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I usually lose a few litres from it pissing out the overflow but fortunately the area I'm driving round is where I go walking. So I go for a nice long walk first to let it and me cool down.

I have been keeping pre mix coolant in the boot as I wouldn't be able to get home without it.

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Ok, just went out for another ride as the last bleed gave good flow.
Went about 3 miles and stopped for a walk. Checked the header and it wasn't overflowing but the cap was hissing. Returned to car and the level was half way between the cold and the top with the cap still on.
Drove home ok, but it is still hissing .

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You sure the O ring in cap isn't torn?

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I will have a closer inspection, It was replaced 18 months ago and on last inspection looked ok.

Just looking into buying a block tester kit £55 looks like a standard piece of kit,always useful to have I guess.

https://www.amazon.co.uk/gp/product/B000RO6CGA/ref=ox_sc_act_title_1?ie=UTF8&psc=1&smid=A327GSNL65G6Q2

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Cap shouldn't hiss unless your hoses feel rock hard......

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For the sake of elimination and a few quid , Ive ordered a new cap along with the block tester kit. should be here Monday but I think that was the start of it before it overheats then overflows. The needle goes from dead centre to red light in seconds .

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Tester kit arrived, negative for gas which is favourable but at the same time annoying as I still cant get to the bottom of it.

I guess the next step is to replace the hoses maybe.

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Buy the infrared thermometer! <br>
You can then look for cold spots, check thermostat opening, find blocked hoses, check rad for even coolant flow, all kinds of fun stuff!

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Just waiting for that to arrive.

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Still waiting for Infrared thermometer to arrive .

about 18 months ago I unfortunately broke down with water pissing out from near the radiator, as soon as you topped up again it just went straight back out. Unfortunately I didnt have much choice due to location and circumstances the car was taken to a stealer of which they were pretty useless and kept saying they couldnt find the problem at first.
Just looking at the history, they replaced the radiator, thermostat , tank cap and some hoses.

http://fl.b5z.net/i/u/6064257/i/ec/COOLING_SYSTEM_HOSES_RANGE_ROVER_FROM_XA.JPG

There are 2 hoses they didnt replace which I am now going to do:
PCH118790 no 8 on the diagram though for some reason island 4x4 state its 94-98 , hopefully an error.

PCH000910 no 7 on diagram. However this one looks a slightly different design . Mine is a solid one piece hose whereas this P/N has a connecting junction and also looks like a larger diameter. Would LR of updated the design but kept the same P/N maybe.

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PCH000910 no 7 on diagram. However this one looks a slightly different design . Mine is a solid one piece hose whereas this P/N has a connecting junction and also looks like a larger diameter. Would LR of updated the design but kept the same P/N maybe <br>
The later production stuff tends to be made from off the shelf discrete components- cheaper to produce, I guess. Just make sure it's not Britpart!

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Yeah thanks, already aware of the blue box company.

The hose I'm looking at is genuine L/R

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Watched an episode of Car SOS, or Wheeler Dealers or something the other evening, where they rebuilt a RR Classic using nothing but Britpart components and panels in a Britpart warehouse (never mentioned by name, but there was a Blue Box in every camera shot!). <br>
Wonder how long that'll last for