Enrichment in acceleration works in different ways depending on age of ECU.
It makes sense to explain how the newer ECUs work first, then it's easier to see why the enrichment in acceleration facility is there at all and why it is more important on older ECUs... Most of you will have the older type ECUs.
On newer ECU's the slider doesn't allow for enrichment at all, full right on the slider gives just the mixture that the map/pressure compensation/temp compensation provides, left of full right leans the mixture during acceleration. On the newer ECUs the only real correct position is full right, anything left of full right points to calibration/setup issues. That's because the newer systems are truly sequential - they take Pinj readings from every petrol injector and (supposedly) each cylinder's gas injector pulse length (Gnj) is calculated individually based on each individual cylinder Pinj's, furthermore the gas pulse should start at almost the same moment that the petrol injector pulse starts (where almost means at the same time or within about 2ms based on other settings such as 'extra injection filtering' where extra injector filtering in theory allows very short Pinj's to be ignored altogether).
The older type AEB based ECU's are not really truly sequential, they take the Pinj reading only from the front cylinder on each bank (blue wires), then each cylinder on the same bank gets the same Ginj as the front cylinder Ginj. Now suppose that between the front cylinder injection pulse and another cylinder's injection pulse on the same bank the driver stamps his foot down... At high rpm the manifold pressure won't have time to increase much before the other cylinders on the same bank inject fuel, at low rpm the manifold pressure will have more time to increase between injection pulses on that bank.. In cases of both high rpm and low rpm the mixture for the rear 3 cylinders (particularly the last cylinder in the firing order) will be leaner than the front cylinder mixture because it didn't read the rear 3 petrol injectors pulse times it just assumed they would be the same as the front cylinder's pulse time. To address this the system has the enrichment in acceleration slider.. The default setting of the slider (usually somewhere near the middle) gives a bit of enrichment to the rear 3 cylinders when the ECU notices manifold pressure and/or Pinj on the front cylinder rising quickly... The enrichment is a fudge, but no more of a fudge than the acceleration enrichment that a petrol ECU provides. Since the newer type ECUs read individual petrol injector pulses to calculate individual gas injector pulses the newer ECUs don't need to add in the fudge themselves because they are reading Pinjs that have already had any necessary acceleration enrichment fudge added by the petrol ECU.
The gas ECU applying an acceleration fudge (instead of the petrol ECU's fudge) isn't really a drawback. The only real drawback of the old type ECU over the new type is that it doesn't necessarily pulse gas injectors at the same time as petrol injectors are pulsed - the new type uses start of petrol injector pulse as trigger for start of gas injector pulse whereas new old type does this for the front cylinder but then spaces the rear 3 cylinder gas injector pulses according to only rpm. Not a problem on older engines but can be a problem on newer engines with features such as VVT/Atkinson cycle.
The acceleration slider won't make any difference to mixture with your foot in a constant position on the throttle, even if you're holding foot flat out, because with constant throttle manifold pressure and Pinj's stay about the same. The slider is used on older ECUs to dial out drive-ability problems when you're changing throttle position (hesitation from lean running with too lean mixture / misfires from too rich), can even be used to compensate a bit for long pipe lengths (needs to be richer during acceleration so more gas reaches the cylinder's intake port in time to make mixture correct with rising manifold pressure). Usually set while the engine is idling then stamping on the throttle (idle to flat out /idle to near flat out / idle to partial throttle) looking for crisp throttle response, and adjusted again while driving.
If you want to change top end mixture while throttle is held constant,you use the other mapping tools (map itself etc). Going too rich on LPG will result in less power than a stoch mixture on LPG because the greater amount of gas displaces what could otherwise be airflow into the engine (hence negatively effecting volumetric efficiency) to a greater extent that going too rich on petrol... You still want a rich mixture at high loads but not always as rich as would make more power on petrol. If you have a 0-1v lambda probe, where on petrol max power might arrive at richer than the narrow band lambda is capable of reading, on LPG max power might arrive at as low as 0,7v but we might still go a bit richer than 0.7v to protect the valves. Set the map first, then adjust the acceleration slider.
Wouldn't bother with a rolling road, they never give same under bonnet temps as driving on a real road. Under bonnet temps effect the LPG vapour temp (and reducer temp) readings which effect the mixture. If you've been sat idling in an LPG car for a while and under bonnet temps get high, if you suddenly set off and boot it the vapour temp reading will for a while be high, causing the mixture to be richer than it will be after a while of driving on the road when vapour temp readings have settled down to normal. Greater volume / faster throughput of gas through the reducer mean that gas temp readings fall when booting it but there is lag between booting it and the temp sensor reflecting the correct temp of gas reaching the injectors - If you have hot under bonnet temps to start with and then set off booting it for a while the mix will start rich and get leaner until temp correction has fully caught up, should be setting mixture when compensation has at least nearly caught up. A rolling road won't keep the rad/engine as cool as real road speeds, AEB systems also compensate mixture for reducer temp. Seat of the pants while reading trims/mixture is probably better than a rolling road.